Relationship between electron affinity and electronegativity periodic trend

relationship between electron affinity and electronegativity periodic trend

These phenomena can be understood in relation to the types of forces holding the This is because of the other trends: ionization energy, electron affinity, and . Major periodic trends include: electronegativity, ionization energy, electron affinity, Ionization energy is the energy required to remove an electron from a neutral atom in The relationship is given by the following equation. Main Difference – Electronegativity vs Electron Affinity Figure 1: Periodic Table of Elements along with Electronegativity of Elements.

Then the atoms can easily attract electrons from the outside. Electronegativity XP from top to bottom of each group The group 17 has the smallest atoms of each period, so it has the highest electronegativity. But the electronegativity decreases down the group because the atomic size increases down the group due to increasing the number of orbitals.

What is Electron Affinity Electron affinity is the amount of energy released when a neutral atom or molecule in the gaseous phase gains an electron from outside. This electron addition causes the formation of a negatively charged chemical species. This can be represented by symbols as follows. This is called exothermic reaction. This reaction results in a negative ion.

But if another electron is going to be added to this negative ion, energy should be given in order to proceed with that reaction. This is because the incoming electron is repelled by the other electrons. This phenomenon is called endothermic reaction. Therefore, the first electron affinities are negative values and the second electron affinity values of the same species are positive values. This is because the incoming electron is added to the outermost orbital of an atom.

The elements of the periodic table are arranged according to the ascending order of their atomic number. When the atomic number increases, the number of electrons they have in their outermost orbitals increases. The General Pattern of Increasing the Electron Affinity along a Period In general, the electron affinity should increase along the period from left to right because the number of electrons increases along a period; thus, it is difficult to add a new electron.

When experimentally analyzed, the electron affinity values show a zig-zag pattern rather than a pattern that shows a gradual increase. Variations of Electron Affinity of Elements The above image shows that the period starting from Lithium Li shows a varying pattern rather than a gradual increase of electron affinity.

Difference Between Electronegativity and Electron Affinity

Beryllium Be comes after Lithium Li in the periodic table, but the electron affinity of Beryllium is lower than Lithium. This is because the incoming electron is taken to the s orbital of Lithium where a single electron is already present. This electron can repel the incoming electron, resulting in a high electron affinity. But in Beryllium, the incoming electron is filled to a free p orbital where no repulsion exists.

Therefore the electron affinity has a slightly lesser value. Electronegativity is the ability of an atom to attract electrons from outside. Electron affinity is the amount of energy released when a neutral atom or molecule in the gaseous phase gains an electron from outside.

relationship between electron affinity and electronegativity periodic trend

Electron shielding is also known as screening. Trends The ionization energy of the elements within a period generally increases from left to right. This is due to valence shell stability. The ionization energy of the elements within a group generally decreases from top to bottom. This is due to electron shielding.

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The noble gases possess very high ionization energies because of their full valence shells as indicated in the graph. Note that helium has the highest ionization energy of all the elements. The relationship is given by the following equation: Unlike electronegativity, electron affinity is a quantitative measurement of the energy change that occurs when an electron is added to a neutral gas atom. This means that an added electron is further away from the atom's nucleus compared with its position in the smaller atom.

With a larger distance between the negatively-charged electron and the positively-charged nucleus, the force of attraction is relatively weaker.

Therefore, electron affinity decreases.

relationship between electron affinity and electronegativity periodic trend

Moving from left to right across a period, atoms become smaller as the forces of attraction become stronger. This causes the electron to move closer to the nucleus, thus increasing the electron affinity from left to right across a period. Note Electron affinity increases from left to right within a period. This is caused by the decrease in atomic radius.

Electron affinity decreases from top to bottom within a group. This is caused by the increase in atomic radius. Atomic Radius Trends The atomic radius is one-half the distance between the nuclei of two atoms just like a radius is half the diameter of a circle.

What is the difference between electronegativity and electron affinity?

However, this idea is complicated by the fact that not all atoms are normally bound together in the same way. Some are bound by covalent bonds in molecules, some are attracted to each other in ionic crystals, and others are held in metallic crystals. Nevertheless, it is possible for a vast majority of elements to form covalent molecules in which two like atoms are held together by a single covalent bond.

This distance is measured in picometers. Atomic radius patterns are observed throughout the periodic table. Atomic size gradually decreases from left to right across a period of elements. This is because, within a period or family of elements, all electrons are added to the same shell. However, at the same time, protons are being added to the nucleus, making it more positively charged.

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The effect of increasing proton number is greater than that of the increasing electron number; therefore, there is a greater nuclear attraction. This means that the nucleus attracts the electrons more strongly, pulling the atom's shell closer to the nucleus. The valence electrons are held closer towards the nucleus of the atom. As a result, the atomic radius decreases. The valence electrons occupy higher levels due to the increasing quantum number n. Note Atomic radius decreases from left to right within a period.

This is caused by the increase in the number of protons and electrons across a period. Atomic radius increases from top to bottom within a group. This is caused by electron shielding. Melting Point Trends The melting points is the amount of energy required to break a bond s to change the solid phase of a substance to a liquid.

Because temperature is directly proportional to energy, a high bond dissociation energy correlates to a high temperature.

Electron Affinity vs Electronegativity - CHEMISTRY COMMUNITY

Melting points are varied and do not generally form a distinguishable trend across the periodic table. However, certain conclusions can be drawn from the graph below. Metals generally possess a high melting point.